Magnificent Entertainer heads toward Hearthome City and befriends the Berry Master. Watch here as his berry powers grow immensely.
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I contacted Dolce and she just told me she can do it sometime tomorrow.
I leveled up the Serperior to level 63, EV trained it (252 SpA / 4 SDef / 252 Spe), and gave it its Life Orb move set (Leaf Storm, Dragon Pulse, Giga Drain, HP Fire), so it will be battle-ready when you receive it.