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Grovyle/Swellow were both Ash's Ace for most of Hoenn, when the Hoenn League came around Glalie made a big impact. Ash's Ace for Unova is debatable, outside of Pikachu none of his other pokemon stood out up until Krokorok evolved into Krookodile. Both Krookodile and Pikachu had good performances...

His Johto pokemon were too weak to be considered Ash's main ace or MVP.He didn't have one in Hoenn or Unova either but Swellow,Grovyle,Glalie,Pikachu and Krookodile were clearly better options than what Ash had to work with in Johto excluding the reserves.

Yeah I don't think he had an ace in Unova,Pikachu was consistently his best,Krookodile beat Iris's Dragonite but it's inflated due to it being disobedient to Iris. Plus Pikachu was the one to defeat Trip's Serperior and came close to taking out 3 of Cameron's pokemon at the league.So it was...

Ash's Hoenn team was very balanced,in the beginning Pikachu was Ash's #1,then eventually it went to Grovyle,once Tailow evolved into Swellow it also had a case for being #1. But I don't think Ash truly had a real ace in Hoenn like he did in OS,DP and XY.Unless we're counting the league where...

Kanto - (Charizard) Orange Islands - (Charizard) Johto - (Charizard) Hoenn - (Swellow)(Grovyle)(Glalie) Battle Frontier - (Sceptile)(Pikachu)(Charizard) Sinnoh - (Infernape) Unova - (Pikachu)(Krookodile) Kalos - (Greninja)