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On one hand based off that end shot in the Bea episode and the revelation she was watching the battle with Volkner I'm expecting Ash to be the one to face Cynthia, and since he probably has to face Leon he likely defeats her. On the other hand perhaps having her lose to the Perfect...

It goes back before even that with Pikachu's habit of frying his best friend at minimal provocation being a recurring gag since pretty much the beginning.