Brock was likely working at the cafe just to woo the girl, and gave up after he found out Kathy had a boyfriend. He hasn't quit his career as a doctor.
https://bulbapedia.bulbagarden.net/wiki/JN139
The third episode of Aim to Be a Pokémon Master has now aired, featuring the return of Brock and Cilan. Feel free to discuss it here.
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