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Chloe actually watched Ash battle for the first time in JN112. This is the first time she watched a PWC match though.

I feel bad for anyone who has to face the wrath of Pikashunium-Z. There’s no way to practice against it, since Ash is the only trainer in the world who can use it. Not to mention that Z-Moves seem to be rare outside of Alola in general. Even though this was the first time it didn’t OHKO on...