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It's not Rica. It is actually an enka singer named Sachiko Kobayashi. She has done some voice acting too. She actually voiced Miranda, the blue-haired girl at the beginning of the movie.

For those who don't know, this is the ending song to the Japanese version of Mewtwo Strikes Back. Give it a listen: https://www.youtube.com/watch?v=MOi6_Km120Y It honestly fits the movie far better than the lame pop songs from the English version. Probably also my favorite Japanese Pokemon anime...