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Well, seeing how Ash has owned a Melmetal (despite it being a Mythical Pokemon) before, I don't see Goh catching a rare Pokemon that isn't very important in how the Pokemon world functions off the table.

Yeah... In fact, I bet that Goh should catch every single Pokemon (regional forms, Legendaries, and Mythics included) before the end of Journeys, something that'll literally render his goal of "gotta catch 'em all" as fulfilled.

IDEK whether Goh will ever catch a Legendary/Mythical Pokemon, but if he were to do so, it'd have to be a body size-1 Legendary/Mythical one because Giratina's quite large.