I agree with Talonflame being the ace, but it's ace ranking stopped at XYZ. IN XYZ, since we got Ash Greninja, that became Ash's new ace for the series until its release. While Talonflame did get many wins before XYZ, after it Greninja was the star and was regarded as the ace.
It seems this is JN084. September 24th is a break because Pokemon’s time slot is taken by Urban Legends 3 hour special. October 15th is also another break because if Pokemon aired then, this would be JN085. AnipokeFandom also says this episode is JN084 on October 22
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