How about...
Venonat and Venomoth - Bug/Psychic
Psyduck and Golduck - Psychic
Drowzee - Poison (it learns Poison Gas, after all)
Hypno - Poison/Dark
Smoochum and Jynx - Psychic/Grass (they should have done this in Alola)
Hoothoot and Noctowl - Psychic/Flying, Ice/Flying or Ghost/Flying (or drop...
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