Because the writers have failed to explain what a Master is (in Movie 20, Ash just said that it was greater than being the best trainer), making it an unachievable goal. As for the Champion League, it hasn't been mentioned in 8 years and merely boils down to the Elite Four challenge, which is...
I don't expect them to call attention to Dexit because it is not as if other regions have featured all Pokemon, either. That said, both XYZ and SM were pretty faithful to the respective regional Pokedexes. The only exceptions that come to mind are Pokemon belonging to characters from other...
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