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I'm afraid they will only appear in a flashback where they say goodbye to Ash while he is on aboard to Ula Ula Island. Ash is going there solo without them.

Could be possible.

Looks like Ash is going there alone after all. No boring school plot segments, but the classmates and Kukui will probably appear at the beginning wondering where he went off to.

Does Popplio appear in this episode? I don't see it at all.

Let's wait.

Uh... Where is the preview for this episode?

Looks like the classmates are here. I wonder if they only appear in the beginning wondering where is Ash or something. Plus, now we know who voices Poipole! It shares the same voice as for Popplio and Munchlax.

Today's the cast list. Let's see if Ash's classmates will be involved in this episode. If not, then Ash and his Mons are going to Ula Ula Island alone.

What about Sophocles? If they are going to Ula'ula Island, maybe he would let his Charjabug evolve there. It's possible.