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Actually it could since it doesn't actually have to damage Guzzlord just hit it with enough force to push it through the ultra wormhole which since it is a giant laser beam it should be able to do. True but, Melmetal also doesn't completely listen to Ash either so that is a point against it...

From this episodes title I am guessing this episode is probably just a means to show off all the Z-Moves that have yet to be seen in the anime (except Mew's) thus clearing up the first plot point they established way at the start of Sun and Moon. Also, possibly will bring back Poipole since...