The four members of the crew announced tonight include:
- The mecha lover Orio (オリオ), who is partnered with a Metagross
- Orio is voiced by Ayane Sakura (佐倉綾音), who previously portrayed Misty in the Pokémon Masters Animated Trailer, and Neesha in Mewtwo Strikes Back - Evolution.
- The skilled cook Murdoch (マードック), who is partnered with a Rockruff
- Murdoch is voiced by Kenta Miyake (三宅健太), who has been the voice of Giovanni since the beginning of Pokémon the Series: Diamond and Pearl, and who also portrayed Cyrus.
- The medical specialist Molly (モリー), whose partner Pokémon is the stereotypical Chansey
- Molly is voiced by voiced by Kei Shindō (真堂圭), whose past Pokémon roles include Serena's rival Miette during Pokémon the Series: XY, Lillie in Pokémon the Series: Sun & Moon, and Nurse Joy in Pokémon Journeys: The Series.
- Lando (ランドウ), a man dressed as a fisherman, who does not have an announced partner Pokémon
- Lando is voiced by Ikkyu Juku (塾一久), who is best known for his portrayal of Daisuke Aramaki in the Ghost in the Shell franchise. This is his first role related to Pokémon.
新シリーズ テレビアニメ「ポケットモンスター」ポケモン博士・フリード率いる「ライジングボルテッカーズ」のメンバーを公開！株式会社小学館集英社プロダクション(ShoPro)のプレスリリース（2023年3月10日 19時30分）新シリーズ テレビアニメ[ポケットモンスター]ポケモン博士・フリード率いる[ライジングボルテッカーズ]のメンバーを公開！prtimes.jp