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Chloe's lookalike is named Soleil (whose dub voice I quite enjoyed), and her Grandmother's name is Helia. The two brothers in the painting were Sorin (the liege) and Luno (the betrayer). The ninja boy is named Ilunas.
Lucien Dodge also marks his return to the main anime after over 8 years.
I'm giving alot of kudos to Cherami Leigh who's pulled off the tones between Chloe (Koharu) and her counterpart, Soleil (Haruhi). Though I have complaints for the dub as to WHY they've picked the name and say that the name Soleil sounds similar to how Chloe's name sounded, for I still fail to see nor hear HOW they sounded similar.