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No one just probably realized to check that. I'm pretty sure that they can be bought from there too, but we need proof to be sure. Maybe I'll replay the remakes at some point and make sure to check it myself.You'd think that Bulbapedia would have that data confirmed by now, since Gen 4 was ages ago. I guess the only way to fully know is to actually buy some Poke Balls at that shop during the time TR is there and see. Like I said, the wiki's data is confusing at best, so it could be possible, but given the shop's "unconventional" nature, it's hard to really say. And I no longer have my copy of either version, so I can't check to confirm it myself. If you're at that point in the game, it might just be better to check yourself. The wiki seems to feel it's not possible to obtain Premier Balls, period, at Mahogany Town, due to it not being a "true" Mart, but it is a rather oddball situation. But I'm willing to bet that TR won't give you a Premier Ball when you buy 10 Poke Balls from there.