JFrombaugh
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Okay so the subtitles confirm that the water splash somehow had the effect of Soak, which is why Pikachu was able to defeat Mudsdale - as that move replaces the opposing Pokémon's type with Water. So I guess at least that's a somewhat better explanation than simply getting splashed with water allows Ground-types to be hit by Electric-type moves if said Electric-type's name is Pikachu.