On the route to Sea Spirit's Den (Azure bay) you can get the Megastone that makes Ampharos Mega envolve, The old man on one of the first islands will give it to you. It is called Ampharosite.
Gogoat pokedex entry,
It can tell how its trainer is feeling by subtle shifts in the grip of its horns. This empathic sense lets them run as if one being.
Skiddo Envolves at lv. 32 to Gogoat
Ability Sap sipper
Skiddo:
Height: 2'11
Weight: 68.3 lbs
Gogoat:
Height: 5'07
Weight: 200.6 lbs
Skiddo can be caught at route 5.
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