Amending this with a self-correction.
There is one random NPC Trainer who uses a Z-Move unannounced. Ace Trainer Lindsey at the Poni Wilds has a Poisonium Z on her Toxapex. Near as I can tell, she is the only instance of this in the entire game.
Weird.
Totem Marowak has busted my shit four times now on my Ultra Sun replay (I’m not allowing the use of Revives, but that’s the only formal restriction). I had an easy time with Totem Araquanid, but only because I’m using a Trumbeak. FTR, my current team is:
Torracat Lv23
Eevee Lv23
Slowpoke Lv23...
On this point, those Trainers actually aren't random. The only Trainers that use Z-Moves (other than the major characters) are a few of the "route bosses," whom you can only challenge after defeating every other Trainer on the route that they govern, and what's more is that these battles have to...
The Alola games and Platinum are the only ones that have ever given me a consistently good challenge, lol. Every other game only has a couple of tough bosses at best.
I agree with the forming consensus that XY are the easiest
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