I discovered the recipes early on; but mainly because I talk to shopkeepers as a general rule. When you interact with the crafting merchant, he gives you the option to buy either recipes or materials in his dialogue. Other than the Piplup sidequest, I don’t think the game mentions that you can...
If your moves are missing frequently, I’d recommend taking a peek at your moveset. A lot of powerful moves tend to have a lower success rate; in a game like this where every turn counts, its better to have a slightly weaker move that hits every time as opposed to an OP move that only has an 85%...
I encountered the same one, forgetting that I had removed Bidoof from my party. I have since encountered all three and finished the request, so unless there’s a random bug you should be able to complete it. Have you left the village and returned to look for it?
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