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The only unbuyable items that should have been buyable were the RageCandyBar and the Slowpoke tail in HGSS.
But seriously, you should be able to buy PP-Related items.
I completely agree! I'm not a huge fan of berry farming since I'm pretty busy, and it was especially annoying how the plants would rot in older games.Ethers! ETHERS!!
I've never understood why we can buy Revives anytime we want, but Ethers and Elixirs have never been purchasable in regular Poké Marts. Once you run out of the ones you find in the overworld, you have to rely on inconsistent, time-consuming methods of getting them like Pickup or Rock Smash. (Or if you're lucky, you can rack up enough BP/FC/Poké Miles to buy some... but no Max Ethers, and no Elixirs.)
I don't like having to ration my stock of Ethers/Elixirs throughout the game, and I especially hate having to become a Leppa Berry farmer just to restore my team's PP during something like the Elite Four. :c