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I got some cheap captures with the Quick Ball, got Palkia and Reshiram first time round. I might have caught Groudon with a Heavy Ball in SS but I had to weaken it for that.
In Sapphire, after two hours of fruitless attempts to capture it before it knocked itself out with Struggle and finally resetting it one last time, I caught Kyogre in one Dive Ball after only two minutes.
Also in White, I caught Zekrom in an ultra ball on the first try, but lost to N, so I soft reset and CAUGHT HIM ON THE FIRST TRY AGAIN. I think that his catch rate is wayyy too high.
I've never caught one on the first throw if I can remember correctly, although I did catch Zekrom with my second thrown great ball which is probably closest I've come
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